α-Amination of Carbonyl Compounds by Using Hypervalent Iodine-Based Aminating Reagents Containing a Transferable (Diarylmethylene)amino Group,Chemistry - A European Journal

当前位置： X-MOL 学术 › Chem. Eur. J. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

α-Amination of Carbonyl Compounds by Using Hypervalent Iodine-Based Aminating Reagents Containing a Transferable (Diarylmethylene)amino Group
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2023-01-05 , DOI: 10.1002/chem.202203722
Daichi Okumatsu ₁ , Kazuki Kawanaka ₁ , Shunpei Kainuma ₁ , Kensuke Kiyokawa ₁ , Satoshi Minakata ₁

Affiliation

Primary resource: Hypervalent iodine-based aminating reagents containing a transferable (diarylmethylene)amino group can be used for the α-amination of simple carbonyl compounds such as esters, amides, and ketones in the presence of a lithium base. The (diarylmethylene)amino groups of the products can be readily modified, thus providing access to primary amines and diarylmethylamines.

中文翻译：

使用含有可转移（二芳基亚甲基）氨基的高价碘基胺化试剂对羰基化合物进行α-胺化

主要资源: 含有可转移（二芳基亚甲基）氨基的高价碘基胺化试剂可用于在锂碱存在下对简单的羰基化合物（如酯、酰胺和酮）进行 α-胺化。产品的（二芳基亚甲基）氨基可以很容易地进行修饰，从而提供获得伯胺和二芳基甲基胺的途径。

更新日期：2023-01-05

点击分享查看原文

点击收藏

阅读更多本刊新发论文