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Ultrathin CuF2-Rich Solid-Electrolyte Interphase Induced by Cation-Tailored Double Electrical Layer toward Durable Sodium Storage
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2023-01-04 , DOI: 10.1002/anie.202216450
Keming Song 1 , Xiang Wang 1 , Zhengkun Xie 1 , Zhiwei Zhao 2 , Zhe Fang 3 , Zhengfeng Zhang 4 , Jun Luo 1 , Pengfei Yan 4 , Zhangquan Peng 2 , Weihua Chen 1, 5
Affiliation  

An ultrathin and CuF2-rich solid-electrolyte interphase is formed on CuS anode via Cu cation-tailored double electrical layer in NaSO3CF3/diglyme electrolyte, which ensures high ion-conductivity and greatly suppresses the electrolyte continuous decomposition. The modified CuS enables high reversible capacity and ultralong cycling life for sodium-ion batteries.

中文翻译:

阳离子定制双电层诱导超薄富含 CuF2 的固体电解质中间相实现持久储钠

在NaSO 3 CF 3 /二甘醇二甲醚电解质中,通过Cu阳离子定制的双电层在CuS负极上形成超薄且富含CuF 2 的固体电解质界面,确保了高离子电导率并极大地抑制了电解质的连续分解。改性 CuS 使钠离子电池具有高可逆容量和超长循环寿命。
更新日期:2023-01-04
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