Quantum Sieving Effects of Ni(bdc)(ted)0.5 and Effective Separation Performance of Ni(bdc)(ted)0.5@γ-Al2O3 for H2/D2,ChemistrySelect

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Quantum Sieving Effects of Ni(bdc)(ted)0.5 and Effective Separation Performance of Ni(bdc)(ted)0.5@γ-Al2O3 for H2/D2
ChemistrySelect ( IF 1.9 ) Pub Date : 2023-01-03 , DOI: 10.1002/slct.202204150
Nan Chen ₁ , Xiaoxiao Chen ₁ , Enming Ping ₁ , Lijuan Zhang ₁ , Yunshan Zhou ₁

Affiliation

Ni(bdc)(ted)_0.5 has chemical affinity quantum sieving (CAQS) effect and kinetic quantum sieving (KQS) effect. Since the adsorption capacity of D₂ in Ni(bdc)(ted)_0.5 is greater than that of H₂, and the diffusion rate at 77 K is lower than that of H₂, Ni(bdc)(ted)_0.5 can achieve the separation of hydrogen and deuterium in gas chromatography.

中文翻译：

Ni(bdc)(ted)0.5的量子筛分效应及Ni(bdc)(ted)0.5@γ-Al2O3对H2/D2的有效分离性能

Ni(bdc)(ted) _0.5具有化学亲和量子筛分（CAQS）效应和动力学量子筛分（KQS）效应。由于D ₂在Ni(bdc)(ted) _0.5中的吸附量大于H ₂，且在77 K时的扩散速率低于H ₂，因此Ni(bdc)(ted) _0.5可以达到在气相色谱中分离氢和氘。

更新日期：2023-01-04

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