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Dynamics and Proton Conduction of Heterogeneously Confined Imidazole in Porous Coordination Polymers
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-12-30 , DOI: 10.1002/anie.202211741
Linkun Cai 1 , Junsheng Yang 1 , Yuyan Lai 1 , Yuling Liang 1 , Rongchun Zhang 1 , Cheng Gu 1 , Susumu Kitagawa 2 , Panchao Yin 1
Affiliation  

Imidazole confined in porous coordination polymers’ channels exhibits dynamics heterogeneity of typical core-shell-cylinder model, in which the core-layer possess faster rotating dynamics contributing to enhanced proton conductivity.

中文翻译:

多孔配位聚合物中非均匀限制咪唑的动力学和质子传导

限制在多孔配位聚合物通道中的咪唑表现出典型核壳圆柱模型的动力学不均匀性,其中核层具有更快的旋转动力学,有助于增强质子传导性。
更新日期:2022-12-30
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