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Weak Electrostatic Interactions with Bisphosphine Ligands Facilitate Reductive Elimination of PhCF3 from Pd(II) Complexes
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2022-12-30 , DOI: 10.1002/asia.202201219
Han Gao 1 , Lingfei Hu 1 , Yanlei Hu 1 , Xiangying Lv 1 , Yan-Bo Wu 2 , Gang Lu 1
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2022-12-30 , DOI: 10.1002/asia.202201219
Han Gao 1 , Lingfei Hu 1 , Yanlei Hu 1 , Xiangying Lv 1 , Yan-Bo Wu 2 , Gang Lu 1
Affiliation
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Energy decomposition analysis reveals that weak electrostatic interactions between bisphosphine ligands and Ph−Pd−CF3 result in high reactivity of PhCF3 reductive elimination from Pd(II) complexes.
中文翻译:
与双膦配体的弱静电相互作用有助于从 Pd(II) 配合物中还原消除 PhCF3
能量分解分析表明,双膦配体与 Ph−Pd−CF 3之间的弱静电相互作用导致 PhCF 3从 Pd(II) 配合物中还原消除的高反应性。
更新日期:2022-12-30
中文翻译:

与双膦配体的弱静电相互作用有助于从 Pd(II) 配合物中还原消除 PhCF3
能量分解分析表明,双膦配体与 Ph−Pd−CF 3之间的弱静电相互作用导致 PhCF 3从 Pd(II) 配合物中还原消除的高反应性。