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An Arbitrarily Regulated Monomer Sequence in Multi-Block Copolymer Synthesis by Frustrated Lewis Pairs
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-12-28 , DOI: 10.1002/anie.202218248
Yi Wan 1 , Jianghua He 1 , Yuetao Zhang 1
Affiliation  

The combination of livingness, dual-initiation, and CSC feature of Lewis pair polymerization enabled the efficient synthesis of well-defined multi-block copolymers from monomer mixtures of methacrylate and acrylates in a one-pot process. Importantly, monomer sequence can be arbitrarily-regulated by changing the composition and adding order of the monomer mixtures.

中文翻译:

受抑路易斯对合成多嵌段共聚物中任意调节的单体序列

Lewis 对聚合的活性、双引发和 CSC 特征的结合使得能够在一锅法中从甲基丙烯酸酯和丙烯酸酯的单体混合物中有效合成明确定义的多嵌段共聚物。重要的是,可以通过改变单体混合物的组成和添加顺序来任意调节单体序列。
更新日期:2022-12-28
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