Metals (Ms) and metal oxides (MOs) possess a strong tendency to coordinate and combine with organic polymers to form respective metal–polymer frameworks (MPFs) and metal oxide polymer frameworks (MOPFs). MPFs and MOPFs can be regarded as composites of organic polymers. MPFs and MOPFs are widely used for industrial and biological applications including as anticorrosive materials in the aqueous phase as well as in the coating conditions. The presence of the Ms and MOs in the polymer coatings improves the corrosion inhibition potential of MPFs and MOPFs by improving their self-healing properties. The Ms and MOs fill the micropores and cracks through which corrosive species such as water, oxygen, and corrosive ions and salts can diffuse and destroy the coating structures. Therefore, the Ms and MOs enhance the durability as well as the effectiveness of the polymer coatings. The present review article is intended to describe the corrosion inhibition potential of some MPFs and MOPFs of some most frequently utilized transition metal elements such as Ti, Si, Zn, Ce, Ag, and Au. The mechanism of corrosion inhibition of MPFs and MOPFs is also described in the presence and absence of metal and metal oxides.

中文翻译：

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作为先进防腐材料的金属和金属氧化物聚合物骨架：设计、性能和未来方向

金属 (Ms) 和金属氧化物 (MOs) 具有很强的配位倾向，可以与有机聚合物结合形成各自的金属-聚合物骨架 (MPF) 和金属氧化物聚合物骨架 (MOPF)。MPFs和MOPFs可视为有机聚合物的复合物。MPF 和 MOPF 广泛用于工业和生物应用，包括在水相和涂层条件下用作防腐材料。Ms 和 MOs 在聚合物涂层中的存在通过提高它们的自修复性能提高了 MPFs 和 MOPFs 的腐蚀抑制潜力。Ms 和 MO 填充微孔和裂缝，水、氧、腐蚀性离子和盐等腐蚀性物质可以通过这些微孔和裂缝扩散并破坏涂层结构。所以，Ms 和 MOs 增强了聚合物涂层的耐用性和有效性。本综述文章旨在描述一些最常用的过渡金属元素（如 Ti、Si、Zn、Ce、Ag 和 Au）的 MPF 和 MOPF 的腐蚀抑制潜力。在存在和不存在金属和金属氧化物的情况下，还描述了 MPF 和 MOPF 的腐蚀抑制机制。