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Structurally Diverse Bench-Stable Nickel(0) Pre-Catalysts: A Practical Toolkit for In Situ Ligation Protocols**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-12-16 , DOI: 10.1002/anie.202211794 Van T Tran 1 , Nana Kim 1 , Camille Z Rubel 1 , Xiangyu Wu 2 , Taeho Kang 1 , Tanner C Jankins 1 , Zi-Qi Li 1 , Matthew V Joannou 3 , Sloan Ayers 3 , Milan Gembicky 4 , Jake Bailey 4 , Emily J Sturgell 1 , Brittany B Sanchez 1 , Jason S Chen 1 , Song Lin 2 , Martin D Eastgate 3 , Steven R Wisniewski 3 , Keary M Engle 1
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-12-16 , DOI: 10.1002/anie.202211794 Van T Tran 1 , Nana Kim 1 , Camille Z Rubel 1 , Xiangyu Wu 2 , Taeho Kang 1 , Tanner C Jankins 1 , Zi-Qi Li 1 , Matthew V Joannou 3 , Sloan Ayers 3 , Milan Gembicky 4 , Jake Bailey 4 , Emily J Sturgell 1 , Brittany B Sanchez 1 , Jason S Chen 1 , Song Lin 2 , Martin D Eastgate 3 , Steven R Wisniewski 3 , Keary M Engle 1
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A series of air-stable Ni0 pre-catalysts of the general type Ni (COD) (L) are described, where L=thiophene oxide, quinone, cyclopentadienone, or fulvene. The properties of the complexes are analyzed through computational and experimental techniques. The precatalysts are competent in a variety of nickel-catalyzed reactions and together constitute a toolkit that overcomes the limitations of both Ni (COD)2 and Ni (COD) (DQ).
中文翻译：
结构多样的台式稳定镍 (0) 预催化剂：原位连接方案的实用工具包**
描述了一系列通用类型Ni (COD) (L)的空气稳定的Ni 0预催化剂，其中L=氧化噻吩、醌、环戊二烯酮或富烯。通过计算和实验技术分析复合物的性质。该预催化剂适用于各种镍催化反应，并共同构成了一个克服 Ni (COD) 2和 Ni (COD) (DQ) 局限性的工具包。
更新日期：2022-12-16
中文翻译：
结构多样的台式稳定镍 (0) 预催化剂：原位连接方案的实用工具包**
描述了一系列通用类型Ni (COD) (L)的空气稳定的Ni 0预催化剂，其中L=氧化噻吩、醌、环戊二烯酮或富烯。通过计算和实验技术分析复合物的性质。该预催化剂适用于各种镍催化反应，并共同构成了一个克服 Ni (COD) 2和 Ni (COD) (DQ) 局限性的工具包。
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