Control of Selectivity in FeCl3-Catalyzed Aerobic Oxidation of Cycloketones,Chemistry - An Asian Journal

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Control of Selectivity in FeCl3-Catalyzed Aerobic Oxidation of Cycloketones
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2022-12-15 , DOI: 10.1002/asia.202201101
Qi Zhao ₁ , Yongtao Wang _{1,

2} , Yu Wang ₁ , Qixuan Hu ₁ , Jia Yao ₁ , Zeyu Wen ₁ , Haoran Li _{1,

3}

Affiliation

An effective approach is reported for selectivity control of FeCl₃-catalyzed oxygenation. For aerobic oxidation of cycloketones in DMSO, it is disclosed that decreasing FeCl₃ loading successfully changes the reaction pathway from C−C cleavage to hydroxylation, and the reductant role of DMSO is emphasized.

中文翻译：