当前位置:
X-MOL 学术
›
Tetrahedron
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Synthesis of acridones through the ring expansion of isatins with arynes oxidated by O2 in air
Tetrahedron ( IF 2.1 ) Pub Date : 2022-12-12 , DOI: 10.1016/j.tet.2022.133209
Zerui Meng , Ran Zhao , Xiaowei Li , Chen Ma , Caixia Xie
中文翻译:
空气中 O2 氧化芳烃与靛红扩环合成吖啶酮
更新日期:2022-12-12
Tetrahedron ( IF 2.1 ) Pub Date : 2022-12-12 , DOI: 10.1016/j.tet.2022.133209
Zerui Meng , Ran Zhao , Xiaowei Li , Chen Ma , Caixia Xie
![]() |
A simple and environmental-friendly method for the construction of acridone derivatives with isatins and arynes was described. The isatins underwent a ring expansion process oxidized by O2 in the air and a broad scope of acridones in moderate to good yields were obtained. Baeyer-Villiger-type oxidation and intermolecular-nucleophilic addition were included, and no extra oxidant except O2 was needed.
中文翻译:

空气中 O2 氧化芳烃与靛红扩环合成吖啶酮
描述了一种用靛红和芳烃构建吖啶酮衍生物的简单且环保的方法。靛红经历了被空气中的 O 2氧化的扩环过程,并以中等至良好的产率获得了广泛的吖啶酮。包括Baeyer-Villiger型氧化和分子间亲核加成,除O 2外不需要额外的氧化剂。