A Series of Low-Coordinate Iron Selenido Complexes: Reactivity of a Linear Iron(I) Silylamide towards Selenium,European Journal of Inorganic Chemistry

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A Series of Low-Coordinate Iron Selenido Complexes: Reactivity of a Linear Iron(I) Silylamide towards Selenium
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2022-12-14 , DOI: 10.1002/ejic.202200706
Christian Schneider ₁ , Sergei Ivlev ₂ , Gunnar Werncke ₃

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We examined the reaction of the linear iron(I) silylamide [Fe(N(Dipp)SiMe₃)₂]^– (Dipp=2,6-diisopropylphenyl) with red selenium. This yields a variety of iron (poly)selenides, and observation of an intramolecular C−H bond activation by a putative terminal iron selenide.

中文翻译：

一系列低配位硒化铁配合物：线性铁 (I) 甲硅烷基酰胺对硒的反应性

_{我们检测了线性铁 (I) 甲硅烷基酰胺 [Fe(N(Dipp)SiMe 3} ) ₂ ] ^– (Dipp=2,6-diisopropylphenyl) 与红硒的反应。这会产生各种铁（聚）硒化物，并观察到推定的末端硒化铁对分子内 C−H 键的激活。

更新日期：2022-12-14

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