Magnetic hybrid material dropped Fe₂O₃ particles in mesoporous carbon was prepared by pyrolysis of MIL-101(Fe) in the presence of nitrogen flow. Then, high activity peroxo-polyoxometallates (Bu₄N)₃PW_xMo_4-x (x = 0, 2, 4) were encapsulated into the magnetic porous carbon material Fe₂O₃/C through facile impregnation method to prepare magnetic supported catalysts (Bu₄N)₃PW_xMo_4-x@Fe₂O₃/C. The catalysts were characterized by several means and applied for extraction oxidation desulfurization (EODS) of model fuel. One synthesized catalyst, (Bu₄N)₃PW₄@Fe₂O₃/C, exhibited nearly perfect catalytic activity, which could remove 99.9 % DBT in simulated fuel within 30 min at mild conditions, and it also showed good activity for other substrate sulfides including BT, 4-MDBT and 4,6-DMDBT. Furthermore, the catalyst (Bu₄N)₃PW₄@Fe₂O₃/C has stable structure and good reusability, which shown removal efficiency of DBT of>90 % up to 8 cycles.

通过在氮气流存在下热解MIL-101(Fe)制备了在介孔碳中滴落Fe ₂ O ₃颗粒的磁性杂化材料。然后，通过简易浸渍法将高活性过氧-多金属氧酸盐(Bu ₄ N) ₃ PW _x Mo _4-x (x = 0, 2, 4)包封到磁性多孔碳材料Fe ₂ O ₃ /C中制备磁性负载催化剂 (Bu ₄ N) ₃ PW _x Mo _4-x @Fe ₂ O ₃/C。催化剂通过多种方式表征，并应用于模型燃料的萃取氧化脱硫（EODS）。合成的一种催化剂(Bu ₄ N) ₃ PW ₄ @Fe ₂ O ₃ /C表现出近乎完美的催化活性，在温和条件下30分钟内可去除模拟燃料中99.9%的DBT，同时对其他催化剂也表现出良好的活性。底物硫化物包括 BT、4-MDBT 和 4,6-DMDBT。此外，该催化剂(Bu ₄ N) ₃ PW ₄ @Fe ₂ O ₃ /C具有稳定的结构和良好的可重复使用性，8个循环后DBT的去除效率>90%。