Chemical Physics ( IF 2.0 ) Pub Date : 2022-12-07 , DOI: 10.1016/j.chemphys.2022.111789
Shuang Lu , Shanshan Hu , Ying Hong , Baolong Wang , Wei Li , Qinyu He , Yinzhen Wang
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Ce3+ and Gd3+ co-doped NaBaBO3 blue luminescent materials were synthesized by the solid-state reaction. X-ray diffraction, X-ray photoelectron spectrometer, and fluorescence spectrometer were used to analyze the crystal structure, the surface morphology, and the luminous properties. Ce3+/Gd3+ co-doped NaBaBO3 phosphors can absorb near-ultraviolet light and emit bright blue light centered at 430 nm, which originates from the 5d-4f transition of Ce3+ ion. When the doping concentration of Ce3+ and Gd3+ was 1 % and 3 % respectively, Ce3+/Gd3+doped NaBaBO3 had the strongest luminous intensity with a short decay time of about 23 ns. The addition of Gd3+ increases the luminescence intensity of Ce3+ doped NaBaBO3. The CIE color coordinates are (0.1564, 0.0909). Ce3+/Gd3+ co-doped NaBaBO3 powders are promising materials for WLEDs and scintillators.
中文翻译:

Ce3+/Gd3+共掺杂NaBaBO3荧光粉的蓝色发光特性
采用固相反应合成了Ce 3+和Gd 3+共掺NaBaBO 3蓝色发光材料。采用X射线衍射仪、X射线光电子能谱仪和荧光光谱仪分析了晶体结构、表面形貌和发光性能。Ce 3+ /Gd 3+共掺杂NaBaBO 3荧光粉可以吸收近紫外光并发出以430 nm为中心的明亮蓝光,这种光来源于Ce 3+离子的5d-4f跃迁。当Ce 3+和Gd 3+的掺杂浓度分别为1 %和3 %时,Ce 3+ /Gd 3+掺杂NaBaBO3具有最强的发光强度,衰减时间短,约为 23 ns。Gd 3+的加入增加了Ce 3+掺杂的NaBaBO 3的发光强度。CIE 颜色坐标为 (0.1564, 0.0909)。Ce 3+ /Gd 3+共掺杂 NaBaBO 3粉末是用于 WLED 和闪烁体的很有前途的材料。
