A Photoenzymatic Strategy for Radical-Mediated Stereoselective Hydroalkylation with Diazo Compounds,Angewandte Chemie International Edition

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A Photoenzymatic Strategy for Radical-Mediated Stereoselective Hydroalkylation with Diazo Compounds
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-12-07 , DOI: 10.1002/anie.202214135
Xinyu Duan ₁ , Dong Cui ₁ , Zhiguo Wang ₂ , Dannan Zheng ₁ , Linye Jiang ₁ , Wen-Yu Huang ₃ , Yi-Xia Jia _{3,

4} , Jian Xu ₁

Affiliation

A photoenzymatic strategy for radical-mediated stereoselective hydroalkylation with diazo compounds has been developed. By this method, a series of γ-chiral carbonyl compounds were synthesized in high yields and stereoselectivities.

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