Assessing Carbazole Derivatives as Single-Electron Photoreductants,The Journal of Organic Chemistry

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Assessing Carbazole Derivatives as Single-Electron Photoreductants
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2022-12-06 , DOI: 10.1021/acs.joc.2c02312
Tyler D Weinhold ₁ , Natalie A Reece ₁ , Kevin Ribeiro ₁ , Maredh Lopez Ocasio ₁ , Noelle Watson ₂ , Kenneth Hanson ₂ , Ashley R Longstreet ₁

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The electron-donating capabilities of carbazoles have stimulated interest in their use as photoinduced single-electron reductants. Due to the modularity of the carbazole, a further broadening and understanding of their reactivity could be achieved by manipulating the structure. Herein, eight carbazole derivatives were synthesized, characterized, and assessed as single-electron photoreductants in the hydrodehalogenation of aryl halides and the arylation of N-methylpyrrole.

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