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通过溶剂同构二面体扭曲控制的伪四面体 [N2O2] 双螯合钴 (II) 单离子磁体的磁各向异性和弛豫
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-12-05 , DOI: 10.1002/chem.202202966 Maximilian H Pohle 1 , Michael Böhme 1 , Thomas Lohmiller 2, 3 , Sven Ziegenbalg 1 , Louis Blechschmidt 1 , Helmar Görls 1 , Alexander Schnegg 2, 4 , Winfried Plass 1
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-12-05 , DOI: 10.1002/chem.202202966 Maximilian H Pohle 1 , Michael Böhme 1 , Thomas Lohmiller 2, 3 , Sven Ziegenbalg 1 , Louis Blechschmidt 1 , Helmar Görls 1 , Alexander Schnegg 2, 4 , Winfried Plass 1
Affiliation
描述了一种基于钴 (II) 的单离子磁体,通过将螯合配体平面之间的二面角扭曲畸变驱动到新的记录水平,可以增加零场分裂。FD-FT THz-EPR 实验用于验证确凿的从头计算和磁化率数据,并启用磁弛豫分析来识别自旋声子耦合过程。
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更新日期:2022-12-05
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