Journal of Sol-Gel Science and Technology ( IF 2.3 ) Pub Date : 2022-12-02 , DOI: 10.1007/s10971-022-05989-5 Anding Huang , Yikun Wu , Zixin Pan , Bangyu Wang , Xiaoping Liang
In order to improve the water resistance of SrAl2O4:Eu2+, Dy3+, the composite long afterglow material Sr2MgSi2O7:Eu2+, Dy3+@ SrAl2O4:Eu2+, Dy3+ was prepared by covering uniform and stable Sr2MgSi2O7 sol on SrAl2O4:Eu2+, Dy3+ powder, which was synthesized via traditional solid-state method. The effects of various factors, such as the amount of ammonia, the molar ratio of Sr2MgSi2O7:SrAl2O4 and the content of H3BO3, on the structure and luminescent properties of Sr2MgSi2O7:Eu2+, Dy3+@ SrAl2O4:Eu2+, Dy3+ were investigated by the response surface method. The results show that the influence extent on both the initial afterglow brightness and water resistance are as follows:the amount of ammonia> the content of H3BO3 > the molar ratio of Sr2MgSi2O7:SrAl2O4. When the amount of ammonia, the molar ratio of Sr2MgSi2O7:SrAl2O4 and the content of H3BO3 is 1.64 mL, 11.10, and 0.006 mol, respectively, both the brightness and water resistance of Sr2MgSi2O7:Eu2+, Dy3+@ SrAl2O4:Eu2+, Dy3+ are improved, the water resistance is 0.835 (51.82% higher than that of pure SrAl2O4) and the initial afterglow brightness can reach 2793 mcd/m2 (91.69% higher than that of pure SrAl2O4), which were in good agreement with the predicted optimum value of 0.867 and 2720 mcd/m2, respectively. Under the optimization conditions, the synergistic action of SrAl2O4 with excellent afterglow properties and Sr2MgSi2O7 with high water resistance plays an important role in improving the water resistance without sacrificing brightness. Finally, the water-based light-emitting inks with SMSA as fluorescent pigment exhibit excellent luminescent properties in the dark.
中文翻译:
复合长余辉材料 Sr2MgSi2O7:Eu2+, Dy3+@ SrAl2O4:Eu2+, Dy3+ 的制备、表征和优化
为了提高SrAl 2 O 4 :Eu 2+ ,Dy 3+的耐水性,复合长余辉材料Sr 2 MgSi 2 O 7 :Eu 2+ ,Dy 3+ @SrAl 2 O 4 :Eu 2+ , Dy 3+由均匀稳定的Sr 2 MgSi 2 O 7溶胶覆盖在SrAl 2 O 4 :Eu 2+ , Dy 3+上制备而成。粉末,这是通过传统的固态方法合成的。氨用量、Sr 2 MgSi 2 O 7 :SrAl 2 O 4摩尔比、H 3 BO 3含量等因素对Sr 2 MgSi 2 O 7结构和发光性能的影响:Eu 2+ , Dy 3+ @ SrAl 2 O 4 :Eu 2+ , Dy 3+采用响应面法进行了研究。结果表明,对初始余辉亮度和耐水性的影响程度为:氨的量>H 3 BO 3的含量>Sr 2 MgSi 2 O 7:SrAl 2 O 4 的摩尔比。当氨的用量、Sr 2 MgSi 2 O 7 :SrAl 2 O 4的摩尔比和H 3 BO 3的含量分别为1.64 mL、11.10和0.006 mol时,Sr 2的亮度和耐水性均硅镁2 O 7 :Eu 2+ , Dy 3+ @SrAl 2 O 4 :Eu 2+ , Dy 3+提高,耐水性为0.835(比纯SrAl 2 O 4提高51.82% )和初始余辉亮度可以达到2793 mcd/m 2(比纯SrAl 2 O 4高91.69% ),分别与预测的最佳值0.867和2720 mcd/m 2非常吻合。在优化条件下,具有优异余辉性能的SrAl 2 O 4与Sr的协同作用2 MgSi 2 O 7具有高耐水性,在提高耐水性而不牺牲亮度方面起着重要作用。最后,以SMSA为荧光颜料的水性发光油墨在黑暗中表现出优异的发光性能。