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An electrocatalytic three-component reaction for the synthesis of phosphoroselenoates
Chemical Communications ( IF 4.3 ) Pub Date : 2022-11-30 , DOI: 10.1039/d2cc05570h
Chi Zhang 1 , Yaqin Zhou 2 , Zhiheng Zhao 2 , Wei Xue 2 , Lijun Gu 2
Chemical Communications ( IF 4.3 ) Pub Date : 2022-11-30 , DOI: 10.1039/d2cc05570h
Chi Zhang 1 , Yaqin Zhou 2 , Zhiheng Zhao 2 , Wei Xue 2 , Lijun Gu 2
Affiliation
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Phosphoroselenoates are important organic molecules because they have found widespread applications in many fields. Herein, an efficient electrochemical dehydrogenative approach to prepare phosphoroselenoates from (hetero)arenes and phosphonates using elemental selenium as the selenium source is reported. This approach is compatible with various functional groups and can be easily scaled up. Our control experiments revealed that electricity plays an important role in this transformation.
中文翻译:
用于合成硒代磷酸酯的电催化三组分反应
硒代磷酸酯是重要的有机分子,因为它们在许多领域都有广泛的应用。在此,报道了一种使用元素硒作为硒源从(杂)芳烃和膦酸酯制备硒代磷酸酯的有效电化学脱氢方法。这种方法与各种功能组兼容,可以轻松扩展。我们的控制实验表明,电力在这种转变中起着重要作用。
更新日期:2022-11-30
中文翻译:

用于合成硒代磷酸酯的电催化三组分反应
硒代磷酸酯是重要的有机分子,因为它们在许多领域都有广泛的应用。在此,报道了一种使用元素硒作为硒源从(杂)芳烃和膦酸酯制备硒代磷酸酯的有效电化学脱氢方法。这种方法与各种功能组兼容,可以轻松扩展。我们的控制实验表明,电力在这种转变中起着重要作用。