Hydrolysis-Induced InOx on ZnIn2S4 Promotes Selective CO2 Photoreduction over H2 Evolution,ChemCatChem

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Hydrolysis-Induced InOx on ZnIn2S4 Promotes Selective CO2 Photoreduction over H2 Evolution
ChemCatChem ( IF 3.8 ) Pub Date : 2022-11-24 , DOI: 10.1002/cctc.202201232
Xinxin Zhang ₁ , Xinkui Wang ₂ , Yuqing Shao ₁ , Zhaolin Dou ₃ , Xiaoyu Liang ₁ , Min Ji ₁ , Min Wang ₃

Affiliation

CO₂ to CO: ZnIn₂S₄ was post-hydrolyzed in an aqueous ammonia solution to form oxide species (ZIS-[InO_x]). Under visible light irradiation, the ZIS-[InO_x] photocatalyst shows enhanced CO₂-to-CO conversion activity. The post hydrolysis treatment significantly prohibits the hydrogen evolution and increases the CO/H₂ ratio from 0.08 over ZIS to 1.8 over ZIS-[InO_x].

中文翻译：

ZnIn2S4 上水解诱导的 InOx 促进选择性 CO2 光还原而不是 H2 释放

CO ₂到CO：ZnIn ₂ S ₄在氨水溶液中后水解以形成氧化物物质(ZIS-[InO _x ])。在可见光照射下，ZIS-[InO _x ] 光催化剂显示出增强的 CO ₂ -to-CO 转化活性。水解后处理显着阻止了氢气的析出，并将 CO/H ₂比率从 ZIS 上的 0.08 提高到 ZIS-[InO _x ] 上的 1.8。

更新日期：2022-11-24

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