A new series of TPATTh-based CMPs have been synthesized via a readily synthetic scheme of C–H direct arylation polymerization (DAP) that involves thiophene-flanked arenes, tris[4-(2-thienyl)phenyl]amine (TPATTh) and commercially available multi-brominated aryls, (2,2′,7,7′-tetrabromo-9,9′-spirobifluorene (TBrSBF), 1,3,6,8-tetrabromopyrene (TBrPy), 2,5-dibromopyrazine (DBrPy), and 1,6-dibromopyrene(DBrPz)). Preactivation of the C–H bonds in the aromatic monomers is not required. The resulting TPATTh-based CMPs display good thermal stability. The porosities of the TPATTh-based CMPs are lain on the structures of the multi-brominated aryls. The TPATTh-based CMPs present good fluorescence emission performances either in the solid states or dispersed in the solvents, and show different colors under 365 ​nm fluorescence irradiation. The resulting TPATTh-based CMPs were used to fluorescence sense to I₂, PA, DNP, and o-NP with high Stern-Volmer quenching constants (Ksv).

通过 C-H 直接芳基化聚合 (DAP) 的简易合成方案合成了一系列新的基于 TPATTh 的 CMP，该方案涉及噻吩侧翼芳烃、三 [4-(2-噻吩基)苯基] 胺 (TPATTh) 和商业化可用的多溴芳基化合物，(2,2',7,7'-tetrabromo-9,9'-spirobifluorene (TBrSBF)、1,3,6,8-四溴芘 (TBrPy)、2,5-二溴吡嗪 (DBrPy) , 和 1,6-二溴芘 (DBrPz))。不需要预先激活芳香族单体中的 C-H 键。由此产生的基于 TPATTh 的 CMP 显示出良好的热稳定性。基于 TPATTh 的 CMP 的孔隙率位于多溴芳基的结构上。基于 TPATTh 的 CMP 在固态或分散在溶剂中均表现出良好的荧光发射性能，并在 365 nm 荧光照射下显示出不同的颜色。生成的 TPATTh-基于 CMP 的荧光检测具有高 Stern-Volmer 淬灭常数 (Ksv) 的 I ₂、PA、DNP 和 o-NP。