Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation,Inorganic Chemistry

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Lanthanide-Anderson Polyoxometalates Frameworks: Efficient Sulfide Photooxidation
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2022-11-23 , DOI: 10.1021/acs.inorgchem.2c03504
De-Gang Ke ₁ , Sheng-Li Huang ₁ , Guo-Yu Yang ₁

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Three polyoxometalate-based metal–organic frameworks were synthesized by the thermal reaction of pyridyl-Anderson polyoxometalate linker and lanthanide ions. With the help of [Ru(bpy)₃]²⁺ photosensitizer, these frameworks exhibited excellent photocatalytic sulfide oxidation performance with sulfoxide selectivity. The reactive oxygen species as well as the photooxidation mechanism were also explored.

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