Gas-Phase Characterization of Hypervalent Carbon Compounds Bearing 7-6-7-Ring Skeleton: Penta- versus Tetra-Coordinate Isomers,Chemistry - A European Journal

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Gas-Phase Characterization of Hypervalent Carbon Compounds Bearing 7-6-7-Ring Skeleton: Penta- versus Tetra-Coordinate Isomers
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-11-23 , DOI: 10.1002/chem.202203163
Satoru Muramatsu ₁ , Keijiro Ohshimo ₂ , Yuan Shi ₁ , Motoki Kida ₁ , Rong Shang ₁ , Yohsuke Yamamoto ₁ , Fuminori Misaizu ₂ , Yoshiya Inokuchi ₁

Affiliation

Hypervalent penta-coordinate carbon compounds were characterized by gas-phase techniques, including photodissociation spectroscopy and ion mobility-mass spectrometry. For a compound with moderate electron-donating ligands bearing p-methylthiophenyl substituents, coexistence of penta- and tetra-coordinate forms was revealed, highlighting the significant effects of the environments on the stability of hypervalent carbons.

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