Journal of Electronic Materials ( IF 2.2 ) Pub Date : 2022-11-18 , DOI: 10.1007/s11664-022-10060-8 Liwen Wang , Haonan Liu , Chengjian Yu , Kaishuo Liu , Hua Wang , Jiwen Xu , Ling Yang , Wei Qiu
(1−x)(K0.5Na0.5)NbO3-xSr(Bi0.5Ta0.5)O3 (KNN-xSBT, x = 0.018, 0.02, 0.022, 0.024, 0.026, 0.028) transparent ferroelectric ceramics were prepared using the solid-phase method. The phase structure, microstructure, light transmittance, and optical and electrical properties of KNN-xSBT were investigated. It was found that the pseudo-cubic phase structure, higher compactness, and smaller grains of KNN can be effectively regulated by introducing the second component, SBT, thus achieving strong light transmittance and good energy storage performance for KNN-xSBT ceramics. When x = 0.022, the near-infrared band (1100 nm) transmittance of the ceramics reaches 72.2%, with energy storage density (Wrec) of 0.53 J/cm3; the maximum dielectric constant is obtained for ceramics at x = 0.018, with a value of 2935. The KNN-xSBT ceramic sample has relaxor ferroelectric properties and is an environmentally friendly lead-free transparent ferroelectric ceramic.
中文翻译:
Sr(Bi0.5Ta0.5)O3改性高透光率(K0.5Na0.5)NbO3铁电陶瓷
(1− x )(K 0.5 Na 0.5 )NbO 3 - x Sr(Bi 0.5 Ta 0.5 )O 3 (KNN- x SBT, x = 0.018, 0.02, 0.022, 0.024, 0.026, 0.028) 透明铁电陶瓷是用固相法。研究了 KNN- x SBT的相结构、微观结构、透光率以及光学和电学性能。发现通过引入第二组分SBT可以有效调节KNN的准立方相结构、更高的致密性和更小的晶粒,从而实现KNN-的强透光性和良好的储能性能。x SBT 陶瓷。当x =0.022时,陶瓷的近红外波段(1100nm)透过率达到72.2%,储能密度(Wrec )为0.53J /cm 3;陶瓷的最大介电常数在x = 0.018 时获得,值为 2935。KNN- x SBT 陶瓷样品具有弛豫铁电特性,是一种环保无铅透明铁电陶瓷。