Single Solution-Phase Synthesis of Charged Covalent Organic Framework Nanosheets with High Volume Yield,Angewandte Chemie International Edition

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Single Solution-Phase Synthesis of Charged Covalent Organic Framework Nanosheets with High Volume Yield
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-11-17 , DOI: 10.1002/anie.202209306
Tong Huang _{1,

2,

3} , Haifei Jiang _{1,

2} , John C Douglin ₄ , Yu Chen ₁ , Shuoyao Yin ₂ , Junfeng Zhang _{2,

5} , Xiaojuan Deng ₆ , Hong Wu ₁ , Yan Yin _{2,

5} , Dario R Dekel _{4,

7} , Michael D Guiver _{2,

5} , Zhongyi Jiang ₁

Affiliation

A single solution-phase synthesis method for charged covalent organic framework nanosheets (COF-NSs) is developed. Charged monomers and appropriate solvent with good solubility and ion dissociation ability are mixed as a high-concentration stable colloidal solution, in which substantial charged COF-NSs are formed via charge-induced in-plane oriented growth, achieving high volume yield.

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