Journal of Solid State Chemistry ( IF 3.2 ) Pub Date : 2022-11-12 , DOI: 10.1016/j.jssc.2022.123718
Linshan Wang , Yanzhen Zeng , Anqing Huang , Shiyun Zhang
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Zn-ion battery has received researcher's interests for nonflammable and clean aqueous electrolyte, cheap and harmless Zn anode. Cathode material plays a vital role in Zn-ion battery, which can influence its performance directly. Because of suitable layer spacing, V2O5 has been considered as a potential cathode material for Zn-ion battery. But its prospect in Zn-ion battery is hindered by low conductivity. To resolve this problem, oxygen defect rich V2O5 (Od-V2O5) is synthesized. It possesses perfect stability when served as cathode material in Zn-ion battery. The specific capacity achieves 425 mAh·g−1 at 0.1 A g−1. Oxygen defect also prompts the separation of electron-hole pairs and makes more electrons participate in photothermal conversion, which boosts photo energy transforms to thermal energy. For Od-V2O5, it shows high photothermal effect efficiency. With Od-V2O5, photothermal membrane is fabricated with electrospinning technique and applied for solar steam generation sea water desalination. Evaporation rate of the membrane reaches 1.29 kg m−2 h−1 with energy conversion efficiency 88.1% under 1 sun irradiation. The energy efficiency keeps stable after continuous evaporation. In evaporated water, the concentration of Na+, K+ Ca2+ and Mg2+ can satisfy the standard of human drinking water. We expect Od-V2O5 has a bright prospect in Zn-ion battery and sea water desalination.
中文翻译:

在 V2O5 中构建氧缺陷以提高锌离子电池和海水淡化的性能
锌离子电池因不易燃、清洁的水性电解质、廉价且无害的锌阳极而受到研究人员的关注。正极材料在锌离子电池中起着至关重要的作用,直接影响其性能。由于适当的层间距,V 2 O 5被认为是锌离子电池的潜在正极材料。但其在锌离子电池中的前景受到低电导率的阻碍。为了解决这个问题,合成了富含氧缺陷的V 2 O 5 ( O d -V 2 O 5 )。用作锌离子电池正极材料时具有完美的稳定性。比容量在0.1 A g时达到425 mAh·g −1-1。氧缺陷还促使电子-空穴对分离,使更多的电子参与光热转换,从而促进光能向热能的转化。对于O d -V 2 O 5,表现出较高的光热效应效率。以O d -V 2 O 5为原料,采用静电纺丝技术制备光热膜,应用于太阳能蒸汽发电海水淡化。膜的蒸发速率达到1.29 kg m −2 h −11个太阳照射下的能量转换效率为88.1%。连续蒸发后能效保持稳定。蒸发水中Na +、K + Ca 2+和Mg 2+的浓度可满足人类饮用水的标准。我们预计O d -V 2 O 5在锌离子电池和海水淡化方面具有广阔前景。
