Single Crystalline, Non-stoichiometric Cocrystals of Hydrogen-Bonded Organic Frameworks,Angewandte Chemie International Edition

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Single Crystalline, Non-stoichiometric Cocrystals of Hydrogen-Bonded Organic Frameworks
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-11-08 , DOI: 10.1002/anie.202215836
Taito Hashimoto ₁ , Ryusei Oketani ₁ , Masaki Nobuoka ₂ , Shu Seki ₂ , Ichiro Hisaki ₁

Affiliation

Proof-of-concept non-stoichiometric cocrystalline frameworks are formed using hexahydropyrene and pyrene derivatives with hydrogen-bonding modules, CP-Hp and CP-Py. The structures and composition ratio were determined by single-crystal X-ray diffraction. Microscopic Raman spectroscopy on a single crystal showed that components are distributed gradationally and/or not homogeneously in the crystal.

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