Phosphor-converted materials have recently become promising candidates for the next generation horticulture and agriculture owing to their ability to overcome the daily sunlight limitations. Here, Tb_0.7La_0.3ZnAl₁₁O₁₉:Cr³⁺ (TLZA:Cr³⁺) was prepared by a high-temperature solid state method, which showed high near-ultraviolet (NUV) and green light to far-red conversion efficiencies. In the optimized TLZA:6%Cr³⁺ phosphor, the energy transfer from the host to the dopant was carried out through a dipole-quadrupole interaction mechanism with an efficiency of 99.62 %. The phosphor-converted light-emitting diode (pc-LED) devices were fabricated by combining TLZA:6%Cr³⁺, blue and red phosphors with 380 nm NUV-chips, which modulated the optimum action spectrum for indoor plant growth. TLZA:6%Cr³⁺ luminescent film laminated glass (LFLG) adjusted the composition of the solar spectrum to red/blue light ratio of 3:1 and promoted plant growth in outdoor horticultural greenhouses. Therefore, the pc-LED and LFLG fabricated with the TLZA:6%Cr³⁺ phosphor in this work are excellent spectral control devices for indoor plant lighting and outdoor horticultural facilities, respectively.

磷转化材料最近成为下一代园艺和农业的有前途的候选者，因为它们能够克服日常的阳光限制。在这里，Tb _0.7 La _0.3 ZnAl ₁₁ O ₁₉ :Cr ³⁺ (TLZA:Cr ³⁺ ) 是通过高温固相法制备的，它显示出高的近紫外 (NUV) 和绿光到远红光的转换效率. 在优化的TLZA:6%Cr ³⁺荧光粉中，从主体到掺杂剂的能量转移通过偶极-四极相互作用机制进行，效率为99.62 %。磷光体转换发光二极管 (pc-LED) 器件是通过结合 TLZA:6%Cr³⁺、蓝色和红色荧光粉，带有 380 nm NUV 芯片，可调节室内植物生长的最佳作用光谱。TLZA:6%Cr ³⁺发光膜夹层玻璃（LFLG）将太阳光谱的组成调整为红/蓝光比为3:1，促进室外园艺温室植物生长。^{因此，本工作中使用 TLZA:6%Cr 3+}荧光粉制造的 pc-LED 和 LFLG分别是室内植物照明和室外园艺设施的优秀光谱控制装置。