Cobalt-Catalyzed Enantioselective Hydroamination of Arylalkenes with Secondary Amines,Angewandte Chemie International Edition

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Cobalt-Catalyzed Enantioselective Hydroamination of Arylalkenes with Secondary Amines
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-11-07 , DOI: 10.1002/anie.202213913
Huanran Miao ₁ , Meihui Guan ₁ , Tao Xiong ₁ , Ge Zhang ₁ , Qian Zhang _{1,

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Affiliation

An excellent enantioselective hydroamination of arylalkenes with Lewis basic secondary amines was developed, via an elegant cobalt-hydride mediated oxidative hydrogen atom transfer (MHAT) process, leading to the synthesis of a series of valuable α-chiral tertiary amines in good to excellent yields and enantioselectivities.

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