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Radical catalysis breaks and makes bonds
Nature Synthesis Pub Date : 2022-11-03 , DOI: 10.1038/s44160-022-00174-6
Lei Gong

Controllable cleavage and conversion of strong C(sp3)–H bonds remains a challenging task in organic synthesis. Here, a reaction design combining hydrogen atom transfer and copper catalysis is developed which allows enantioselective alkene difunctionalization using aliphatic C–H bond activation.

中文翻译:

自由基催化断裂并形成键

强 C(sp3)-H 键的可控裂解和转化仍然是有机合成中的一项具有挑战性的任务。在这里,开发了一种结合氢原子转移和铜催化的反应设计,该设计允许使用脂肪族 C-H 键活化进行对映选择性烯烃双官能化。
更新日期:2022-11-04
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