用于高效离子传输的工程聚合物纳米流体膜：仿生设计、材料构造和高级功能,ACS Nano

当前位置： X-MOL 学术 › ACS Nano › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

用于高效离子传输的工程聚合物纳米流体膜：仿生设计、材料构造和高级功能
ACS Nano ( IF 15.8 ) Pub Date : 2022-11-02 , DOI: 10.1021/acsnano.2c07641
Xia-Chao Chen ₁ , Hao Zhang ₁ , Sheng-Hua Liu ₁ , Yahong Zhou ₂ , Lei Jiang ₂

Affiliation

从生物离子通道中提取的设计元素指导人工纳米流体膜的工程设计，以实现高效的离子传输，并催生出在许多前沿领域具有巨大潜力的仿生设备。在这种情况下，聚合物纳米流体膜因其固有的灵活性和良好的可加工性而特别有吸引力，这有助于大规模制造和简便的设备集成以用于大规模应用。在此，系统地总结了聚合物纳米流体膜的最新成就。介绍了生物和合成离子通道的基础理论基础。然后从结构设计、材料构建和化学功能化等方面详细介绍了工程聚合物纳米流体膜的进展，强调其广泛的化学和网状/拓扑多样性以及相当大的性能可调性。之后，本综述详述了将这些聚合物膜演变成宏观装置的示例，以及它们在解决能量转换和存储系统中非常需要高效离子传输的紧迫问题方面的潜力。最后，对该领域可能的未来发展进行了简要展望。

"点击查看英文标题和摘要"

Engineering Polymeric Nanofluidic Membranes for Efficient Ionic Transport: Biomimetic Design, Material Construction, and Advanced Functionalities

Design elements extracted from biological ion channels guide the engineering of artificial nanofluidic membranes for efficient ionic transport and spawn biomimetic devices with great potential in many cutting-edge areas. In this context, polymeric nanofluidic membranes can be especially attractive because of their inherent flexibility and benign processability, which facilitate massive fabrication and facile device integration for large-scale applications. Herein, the state-of-the-art achievements of polymeric nanofluidic membranes are systematically summarized. Theoretical fundamentals underlying both biological and synthetic ion channels are introduced. The advances of engineering polymeric nanofluidic membranes are then detailed from aspects of structural design, material construction, and chemical functionalization, emphasizing their broad chemical and reticular/topological variety as well as considerable property tunability. After that, this Review expands on examples of evolving these polymeric membranes into macroscopic devices and their potentials in addressing compelling issues in energy conversion and storage systems where efficient ion transport is highly desirable. Finally, a brief outlook on possible future developments in this field is provided.

更新日期：2022-11-02

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南