The Transformation of Inorganic to Organic Carbonates: Chasing for Reaction Pathways in Mechanochemistry,Chemistry - A European Journal

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The Transformation of Inorganic to Organic Carbonates: Chasing for Reaction Pathways in Mechanochemistry
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2022-10-31 , DOI: 10.1002/chem.202202860
Miriam Sander ₁ , Sven Fabig ₁ , Lars Borchardt ₁

Affiliation

The synthesis of the green organic solvent diethyl carbonate by mechanochemistry starting from inorganic carbonates is used as target system to light up the ‘black box’ with its heavily vibrating, dense milling vessels. The complementary combination of milling parameter studies, synchrotron X-ray diffraction real time monitoring, and quantum chemical calculations reveals the underlying reaction pathways and intermediates.

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