Applied Surface Science ( IF 6.3 ) Pub Date : 2022-10-29 , DOI: 10.1016/j.apsusc.2022.155477
I. Palacio , J. Obando-Guevara , L. Chen , M.N. Nair , M.A. González Barrio , E. Papalazarou , P. Le Fèvre , A. Taleb-Ibrahimi , E.G. Michel , A. Mascaraque , A. Tejeda
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We have studied the temperature-dependent electronic structure of the light rare-earth antimonide LaSb2 by combining angle-resolved photoemission (ARPES) measurements and density functional theory (DFT) calculations. ARPES measurements show the appearance of band replicas in the low-temperature Fermi surface with q = 0.25 ± 0.02 A−1 and a band folding of the same periodicity with a considerable spectral weight in the folded band. From our calculations we elucidate that the folded band exhibiting the new periodicity is associated with the La-Sb layer. We propose that an in-plane distortion, probably affecting the whole unit cell, is the structural modification related to the electronic changes. All these results converge to support that a charge density wave is stabilized in LaSb2 at low temperature.
中文翻译:

LaSb2 的费米面和 CDW 跃迁的直接观察
我们通过结合角度分辨光电发射 (ARPES) 测量和密度泛函理论 (DFT) 计算,研究了轻稀土锑化物 LaSb 2的温度相关电子结构。ARPES 测量显示在低温费米表面中出现带复制品,q = 0.25 ± 0.02 A -1和具有相同周期性的带折叠,折叠带中有相当大的光谱权重。从我们的计算中,我们阐明了表现出新周期性的折叠带与 La-Sb 层有关。我们提出,可能影响整个晶胞的面内变形是与电子变化相关的结构修改。所有这些结果都收敛于支持电荷密度波在 LaSb 中是稳定的2低温。