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A Solid Oxide Fuel Cell Runs on Hydrocarbon Fuels with Exceptional Durability and Power Output
Advanced Energy Materials ( IF 24.4 ) Pub Date : 2022-10-27 , DOI: 10.1002/aenm.202202928
Weilin Zhang 1 , Xueyu Hu 1 , Yucun Zhou 1 , Zheyu Luo 1 , Gyutae Nam 1 , Yong Ding 1 , Tongtong Li 1 , Zhijun Liu 1 , Yoojin Ahn 1 , Nicholas Kane 1 , Weining Wang 1 , Jie Hou 1 , Drew Spradling 2 , Meilin Liu 1
Affiliation  

Solid oxide fuel cells (SOFCs) that can operate on hydrocarbon fuels offer an efficient and cost-effective solution for electricity generation. However, broader commercialization of SOFCs is hindered by inadequate performance and limited durability due to the sluggish hydrocarbon reforming/oxidation kinetics and coking on the SOFC anode. Here it has been reported that these findings in design, synthesis, and characterization of a novel anode catalyst Ba(Zr0.8Y0.2)0.9(Ni0.5Ru0.5)0.1O3-δ (BZYNR) that overcomes the problems, enabling direct utilization of nearly dry hydrocarbon fuels (e.g., methane, ethanol, and iso-octane with only 3 vol% H2O) with exceptional power output for over 1000 h on both button cells and tubular cells. The outstanding performance of BZYNR is attributed to the high activity of hydrocarbon reforming and the accelerated water-mediated carbon cleaning process on Ni-based SOFC anode.

中文翻译:

固体氧化物燃料电池以碳氢化合物燃料运行,具有出色的耐用性和功率输出

可以使用碳氢化合物燃料运行的固体氧化物燃料电池 (SOFC) 为发电提供了一种高效且具有成本效益的解决方案。然而,由于碳氢化合物重整/氧化动力学缓慢和 SOFC 阳极结焦,SOFC 的性能不足和耐久性有限,阻碍了 SOFC 的更广泛商业化。据报道,在新型阳极催化剂 Ba(Zr 0.8 Y 0.2 ) 0.9 (Ni 0.5 Ru 0.5 ) 0.1 O 3-δ (BZYNR)的设计、合成和表征中的这些发现克服了这些问题,实现了直接利用几乎干燥的碳氢化合物燃料(例如,甲烷、乙醇和仅含 3 vol% H 2的异辛烷)O) 在纽扣电池和管状电池上都具有超过 1000 小时的出色功率输出。BZYNR 的出色性能归因于碳氢化合物重整的高活性和镍基 SOFC 阳极上加速的水介导的碳清洁过程。
更新日期:2022-10-27
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