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Enantioselectivity in the toxicological effects of chiral pesticides: A review
Science of the Total Environment ( IF 8.2 ) Pub Date : 2022-10-22 , DOI: 10.1016/j.scitotenv.2022.159656 Chenyang Ji 1 , Zhongdi Song 1 , Zhongling Tian 1 , Zixuan Feng 1 , Lele Fan 1 , Chenfei Shou 1 , Meirong Zhao 2
Science of the Total Environment ( IF 8.2 ) Pub Date : 2022-10-22 , DOI: 10.1016/j.scitotenv.2022.159656 Chenyang Ji 1 , Zhongdi Song 1 , Zhongling Tian 1 , Zixuan Feng 1 , Lele Fan 1 , Chenfei Shou 1 , Meirong Zhao 2
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As a special category of pesticides, chiral pesticides have increased the difficulty in investigating pesticide toxicity. Based on their usage, chiral pesticides can be divided into insecticides, herbicides, and fungicides. Over the past decades, great efforts have been made on elucidating their toxicological effects. However, no literature has reviewed the enantioselective toxicity of chiral pesticides since 2014. In recent years, more chiral pesticides have been registered for application. As such, huge research progresses have been achieved in enantioselective toxicity of chiral pesticides. Generally, more researches have remedied the knowledge gap in toxicological effects of old and new chiral pesticides. And the toxicological endpoints being evaluated have become more specific rather than centering on basic toxicity and target organisms. Besides, the underlying mechanisms accounting for the enantioselectivity in toxicological effects of chiral pesticides have been discussed as well. All in all, this review provides the critical knowledge for risk assessments, and help to drive the green-technology of single- or enriched-enantiomer pesticides and formulation of relevant laws and regulations.
中文翻译：
手性农药毒理学作用中的对映选择性：综述
手性农药作为一类特殊的农药，增加了农药毒性调查的难度。根据它们的用途，手性农药可分为杀虫剂、除草剂和杀菌剂。在过去的几十年里，人们在阐明其毒理学影响方面付出了巨大努力。然而，自 2014 年以来，没有文献回顾手性农药的对映选择性毒性。近年来，越来越多的手性农药被登记应用。因此，手性农药的对映选择性毒性取得了巨大的研究进展。总的来说，更多的研究弥补了新旧手性农药毒理学效应方面的知识空白。正在评估的毒理学终点变得更加具体，而不是以基本毒性和目标生物为中心。此外，还讨论了解释手性农药毒理学作用对映选择性的潜在机制。总而言之，本综述为风险评估提供了关键知识，有助于推动单一或富集对映异构体农药的绿色技术以及相关法律法规的制定。
更新日期：2022-10-22
中文翻译：
手性农药毒理学作用中的对映选择性：综述
手性农药作为一类特殊的农药，增加了农药毒性调查的难度。根据它们的用途，手性农药可分为杀虫剂、除草剂和杀菌剂。在过去的几十年里，人们在阐明其毒理学影响方面付出了巨大努力。然而，自 2014 年以来，没有文献回顾手性农药的对映选择性毒性。近年来，越来越多的手性农药被登记应用。因此，手性农药的对映选择性毒性取得了巨大的研究进展。总的来说，更多的研究弥补了新旧手性农药毒理学效应方面的知识空白。正在评估的毒理学终点变得更加具体，而不是以基本毒性和目标生物为中心。此外，还讨论了解释手性农药毒理学作用对映选择性的潜在机制。总而言之，本综述为风险评估提供了关键知识，有助于推动单一或富集对映异构体农药的绿色技术以及相关法律法规的制定。
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