TBD (1,5,7-triazabicyclo[4.4.0]dec-5-ene) is an organic superbase with unique catalytic effects due to its bifunctionality. It is already successfully used as a versatile catalyst, e.g., for transesterification, amidation, Michael addition, and aldol reactions, in technical silicone chemistry and even for enantioselective transformations. Currently, main applications are in innovative polymer chemistry (vitrimers, nonisocyanate polyurethanes, and polyureas). Restrictions of a broader application of TBD in technical processes due to its limited market availability and the complicated handling of its crystalline delivery form are now overcome by a simple one-pot synthesis of TBD, which generates an easy-to-make, ready-to-apply liquid formulation.

中文翻译：

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独特的超级碱 TBD（1,5,7-三氮杂双环[4.4.0]dec-5-ene）：从催化活性和一锅法合成到在工业化学中的更广泛应用

TBD (1,5,7-triazabicyclo[4.4.0]dec-5-ene) 是一种有机超级碱，由于其双功能性而具有独特的催化作用。它已经成功地用作一种多功能催化剂，例如用于酯交换、酰胺化、迈克尔加成和羟醛反应，用于技术有机硅化学，甚至用于对映选择性转化。目前，主要应用在创新的高分子化学领域（玻璃聚合物、非异氰酸酯聚氨酯和聚脲）。由于 TBD 的市场可用性有限以及其结晶交付形式的复杂处理，限制了 TBD 在技术过程中更广泛的应用，现在通过简单的 TBD 的一锅法合成来克服，它生成易于制作、即用的- 应用液体配方。