Chiral Mesostructured Inorganic Materials with Optical Chiral Response,Advanced Materials

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Chiral Mesostructured Inorganic Materials with Optical Chiral Response
Advanced Materials ( IF 27.4 ) Pub Date : 2022-10-17 , DOI: 10.1002/adma.202205088
Yingying Duan ₁ , Shunai Che ₂

Affiliation

Fabricating chiral inorganic materials and revealing their unique quantum confinement-determined optical chiral responses are crucial tasks in the multidisciplinary fields of chemistry, physics, and biology. The field of chiral mesostructured inorganic materials started from the synthesis of individual nanocrystals and evolved to include their assembly from metals, semiconductors, ceramics, and inorganic salts endowed with various chiral structures ranging from atomic to micron scales. This tutorial review highlights the recent research on chiral mesostructured inorganic materials, especially the novel expression of mesostructured chirality and endowed optical chiral response, and it may inspire us with new strategies for the design of chiral inorganic materials and new opportunities beyond the traditional applications of chirality. Fabrication methods for chiral mesostructured inorganic materials are classified according to chirality type, scale, and symmetry-breaking mechanism. Special attention is given to highlight systems with original discoveries, exceptional phenomena, or unique mechanisms of optical chiral response for left- and right-handedness.

中文翻译：

具有光学手性响应的手性介观结构无机材料

制造手性无机材料并揭示其独特的量子限制决定的光学手性响应是化学、物理和生物学多学科领域的关键任务。手性介观结构无机材料领域从单个纳米晶体的合成开始，发展到包括具有从原子到微米尺度的各种手性结构的金属、半导体、陶瓷和无机盐的组装。本教程综述重点介绍了手性介观无机材料的最新研究，特别是介观结构手性和赋予光学手性响应的新颖表达，它可能会启发我们设计手性无机材料的新策略和超越手性传统应用的新机遇。手性介观结构无机材料的制备方法根据手性类型、规模和对称性破缺机制进行分类。特别关注具有原创发现、特殊现象或左旋和右旋光学手性响应独特机制的突出系统。

更新日期：2022-10-17

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