General Access to N−CF3 Secondary Amines and Their Transformation to N−CF3 Sulfonamides,Angewandte Chemie International Edition

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General Access to N−CF3 Secondary Amines and Their Transformation to N−CF3 Sulfonamides
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-10-12 , DOI: 10.1002/anie.202212115
Leibing Wang ₁ , Jieping Wang ₁ , Sitao Ye ₁ , Beihan Jiang ₁ , Zihao Guo ₁ , Yasir Mumtaz ₁ , Wenbin Yi ₁

Affiliation

A new and mild method for the generation of HF from triethylsilane and silver fluoride leads to a highly efficient one-pot synthesis of N−CF₃ secondary amines. Novel N−CF₃ sulfonamides were constructed from these promising amine building blocks and sulfonyl bromides in an unprecedented route.

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