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H2O Activity Adjustment by Hydrogen Bonding Enables High-Performance Zn-Organic Battery
ChemSusChem ( IF 7.5 ) Pub Date : 2022-10-11 , DOI: 10.1002/cssc.202201739
Kang Zhou 1 , Nan Wang 1 , Xuan Qiu 1 , Haijiao Xie 2 , Peng Wei 3 , Xiaoli Dong 1 , Yonggang Wang 1
ChemSusChem ( IF 7.5 ) Pub Date : 2022-10-11 , DOI: 10.1002/cssc.202201739
Kang Zhou 1 , Nan Wang 1 , Xuan Qiu 1 , Haijiao Xie 2 , Peng Wei 3 , Xiaoli Dong 1 , Yonggang Wang 1
Affiliation
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No water, no problem: The H2O activity in aqueous electrolyte is restrained by adding glycerol and acetonitrile into the electrolyte to form hydrogen bonds between organic solvents and H2O molecules, which facilities the smooth Zn deposition and alleviates Zn corrosion. Therefore, the Zn//Zn symmetrical cell cycles for over 1300 h and the Zn//FD28 full cell cycles for 9000 cycles.
中文翻译:
通过氢键调节 H2O 活性可实现高性能锌有机电池
没有水,没问题:通过在电解液中加入甘油和乙腈,使有机溶剂与H 2 O分子形成氢键,从而抑制水系电解液中H 2 O的活性,从而促进Zn的顺利沉积,减轻Zn的腐蚀。因此,Zn//Zn 对称细胞循环超过 1300 小时,Zn//FD28 全细胞循环为 9000 个循环。
更新日期:2022-10-11
中文翻译:

通过氢键调节 H2O 活性可实现高性能锌有机电池
没有水,没问题:通过在电解液中加入甘油和乙腈,使有机溶剂与H 2 O分子形成氢键,从而抑制水系电解液中H 2 O的活性,从而促进Zn的顺利沉积,减轻Zn的腐蚀。因此,Zn//Zn 对称细胞循环超过 1300 小时,Zn//FD28 全细胞循环为 9000 个循环。