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Phosphorus based hybrid materials for green fuel generation
Wiley Interdisciplinary Reviews: Energy and Environment ( IF 5.4 ) Pub Date : 2022-10-05 , DOI: 10.1002/wene.458 Srabanti Ghosh 1, 2 , Susmita Bera 1 , Soumita Samajdar 1, 2 , Sourabh Pal 1
Wiley Interdisciplinary Reviews: Energy and Environment ( IF 5.4 ) Pub Date : 2022-10-05 , DOI: 10.1002/wene.458 Srabanti Ghosh 1, 2 , Susmita Bera 1 , Soumita Samajdar 1, 2 , Sourabh Pal 1
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Phosphorene, also referred to as phosphorus-based elemental material (black and red), display unusual electronic-structure characteristics, which can significantly enrich the fields of energy application and possesses huge potential in photocatalysis owing to its bandgap tunability, high optical absorption, large surface area, high charge carrier mobilities, and efficient solar to chemical energy conversion. However, due to chemical instability and the poor visible-light utilization efficiency, individual phosphorus materials cannot promote charge transfer and separation. For designing active photocatalysts, phosphorus-based hybrid materials with effective charge carriers separation at the heterojunction interface has played significant role. In this respect, considerable attempts have been made to fabricate black–red phosphorus heterostructure for photocatalytic applications and solar fuel generation, such as photocatalytic and electrocatalysis water splitting, CO2 reduction, carbohydrates synthesis, etc. This review article highlights the strategies for the synthesis of black–red phosphorus heterostructure materials for catalysis with a special focus on their potential for solar fuel generation applications. Recently developed black–red phosphorus heterostructure will be discussed, which can improve the most challenging drawback of phosphorus materials. Finally, the major challenges along with future trends of black–red phosphorus heterostructure in catalytic applications are outlined.
中文翻译：
用于绿色燃料发电的磷基混合材料
磷烯又称磷基单质材料（黑色和红色），具有独特的电子结构特征，具有带隙可调性、高光吸收性、大的光催化特性，可显着丰富能源应用领域，在光催化领域具有巨大潜力。表面积、高电荷载流子迁移率和高效的太阳能到化学能的转换。然而，由于化学不稳定和可见光利用效率差，单个磷材料不能促进电荷转移和分离。对于设计活性光催化剂，在异质结界面具有有效载流子分离的磷基杂化材料发挥了重要作用。在这方面，2还原、碳水化合物合成等。这篇综述文章重点介绍了用于催化的黑-红磷异质结构材料的合成策略，特别关注它们在太阳能燃料发电应用中的潜力。将讨论最近开发的黑-红磷异质结构，它可以改善磷材料最具挑战性的缺点。最后，概述了黑-红磷异质结构在催化应用中的主要挑战以及未来趋势。
更新日期：2022-10-05
中文翻译：
用于绿色燃料发电的磷基混合材料
磷烯又称磷基单质材料（黑色和红色），具有独特的电子结构特征，具有带隙可调性、高光吸收性、大的光催化特性，可显着丰富能源应用领域，在光催化领域具有巨大潜力。表面积、高电荷载流子迁移率和高效的太阳能到化学能的转换。然而，由于化学不稳定和可见光利用效率差，单个磷材料不能促进电荷转移和分离。对于设计活性光催化剂，在异质结界面具有有效载流子分离的磷基杂化材料发挥了重要作用。在这方面，2还原、碳水化合物合成等。这篇综述文章重点介绍了用于催化的黑-红磷异质结构材料的合成策略，特别关注它们在太阳能燃料发电应用中的潜力。将讨论最近开发的黑-红磷异质结构，它可以改善磷材料最具挑战性的缺点。最后，概述了黑-红磷异质结构在催化应用中的主要挑战以及未来趋势。
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