Remote Editing of Stacked Aromatic Assemblies for Heteroannular C−H Functionalization by a Palladium Switch between Aromatic Rings,Angewandte Chemie International Edition

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Remote Editing of Stacked Aromatic Assemblies for Heteroannular C−H Functionalization by a Palladium Switch between Aromatic Rings
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-10-04 , DOI: 10.1002/anie.202212079
Zhiqian Yu ₁ , Qianhui Liu ₁ , Qian Li ₁ , Zhenmei Huang ₁ , Yudong Yang ₁ , Jingsong You ₁

Affiliation

A transient ligand-enabled palladium-catalyzed heteroannular C−H olefination and allylation of stacked aromatic assemblies has been developed, in which the remote heteroannular site over the proximal homoannular site is functionalized. Mechanistic investigations support an olefin coordination-promoted interannular palladium migration process determinative for reversal of the site-selectivity.

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