Mechanochemical Electrophilic Mono- or Disulfur Transfer: Construction of P(O)–S or P(O)–S–S Bonds,Organic Letters

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Mechanochemical Electrophilic Mono- or Disulfur Transfer: Construction of P(O)–S or P(O)–S–S Bonds
Organic Letters ( IF 4.9 ) Pub Date : 2022-09-28 , DOI: 10.1021/acs.orglett.2c03018
Ziwu Zhang ₁ , Tianfeng Lao ₁ , Lichan Deng ₁ , Chen Zhang _{1,

2} , Jubin Liu ₁ , Min Fu ₁ , Zhengquan Su ₁ , Yue Yu _{1,

3} , Hua Cao _{1,

3}

Affiliation

Under mechanochemically induced conditions, a wide range of diarylphosphine oxides or H-phosphonates react with trisulfide dioxides to afford various thiophosphate derivatives in good yields. Selective S–S bond cleavage of trisulfide dioxides determined by connecting groups is proposed as the key step in the construction of P(O)–S or P(O)–S–S bonds, which is supported by calculations.

中文翻译：

机械化学亲电单硫或二硫转移：P(O)-S 或 P(O)-S-S 键的构建

在机械化学诱导的条件下，多种二芳基膦氧化物或H-膦酸盐与二氧化三硫化物反应以良好的收率提供各种硫代磷酸盐衍生物。由连接基团确定的二氧化三硫的选择性 S-S 键断裂被认为是构建 P(O)-S 或 P(O)-S-S 键的关键步骤，这得到了计算的支持。

更新日期：2022-09-28

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