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Surface modification of poly(propylene) fabric with graphene oxide-based silver nanoparticles for antibacterial applications
Journal of Applied Polymer Science ( IF 2.7 ) Pub Date : 2022-09-23 , DOI: 10.1002/app.53119
Nguyen Minh Dat 1, 2, 3 , Le Minh Huong 1, 2, 3 , Ninh Thi Tinh 1, 2, 3 , Nguyen Thi Thuy Linh 1, 2, 3 , Nguyen Duy Hai 1, 2, 3 , Nguyen Duc Viet 1, 2, 3 , Doan Ba Thinh 1, 2, 3 , Che Quang Cong 1, 2, 3 , Nguyen Tien Dat 3, 4 , Mai Thanh Phong 1, 2, 3 , Nguyen Huu Hieu 1, 2, 3
Affiliation  

Herein, poly(propylene) (PP) was hydrophilized with oxidating agents and solvents, followed by dip-coating with silver nanoparticles anchored GO sheets (Ag@GO) prepared by the in-situ method as reported in our previous study to obtain silver@graphene oxide-coated poly(propylene) (Ag@GO/PP). The impact of the modifying agents, dipping times, and coating concentrations on the antibacterial activities were studied accordingly via the inhibition zone method. The fabrics were re-hydrophobized with the reduction of Ag@GO and the functionalization with stearic acid (SA) to form silver@reduced graphene oxide-coated poly(propylene) (Ag@rGO/PP) and silver@graphene oxide/SA-coated poly(propylene) (Ag@rGO-SA/PP), respectively. Characterization of pretreated and modified PP samples was carried out by various modern analysis methods. Simultaneously, the cytotoxicity of the active layers, the release of Ag+ ions, and durability after washing were also investigated. The obtained results representing PP fabrics pretreated with HNO3/isopropanol and dipped in Ag@GO concentration of 2 g/L four times prove a sufficient approach for improving hydrophilization and bio-compatibility for the PP samples. The fabrics greatly show an impressive interaction with precursors, mostly high antibacterial activity even after four washing cycles via appropriate releasing of Ag+ to ensure the safety in usage. They further suggest that the prepared fabrics could be utilized for actual application as a face mask.

中文翻译:

用于抗菌应用的氧化石墨烯基银纳米粒子对聚丙烯织物的表面改性

在这里,聚(丙烯)(PP)用氧化剂和溶剂亲水化,然后用我们之前研究中报道的原位方法制备的银纳米颗粒锚定的GO片材(Ag@GO)浸涂以获得银@氧化石墨烯涂层的聚(丙烯)(Ag@GO/PP)。通过抑菌圈法研究了改性剂、浸渍时间和包衣浓度对抗菌活性的影响。织物通过还原 Ag@GO 和用硬脂酸 (SA) 功能化重新疏水化,形成银@还原氧化石墨烯包覆的聚丙烯 (Ag@rGO/PP) 和银@氧化石墨烯/SA-涂层聚(丙烯)(Ag@rGO-SA/PP),分别。通过各种现代分析方法对预处理和改性 PP 样品进行了表征。同时,+离子和洗涤后的耐久性也进行了研究。所获得的 PP 织物用 HNO 3 /异丙醇预处理并浸入浓度为 2 g/L 的 Ag@GO 中四次的结果证明是提高 PP 样品的亲水性和生物相容性的充分方法。该织物与前体的相互作用非常显着,即使经过四次洗涤循环后,通过适当释放Ag +以确保使用安全,大多数情况下仍具有很高的抗菌活性。他们进一步建议,制备的织物可用于实际应用作为面罩。
更新日期:2022-09-23
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