Modular Approach for Diversity-Oriented Synthesis of β-Fluoroalkylated Arenes via Pd/Norbornene Cooperative Catalysis,Chemistry - An Asian Journal

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Modular Approach for Diversity-Oriented Synthesis of β-Fluoroalkylated Arenes via Pd/Norbornene Cooperative Catalysis
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2022-09-22 , DOI: 10.1002/asia.202200858
Shuxin Chen ₁ , Xue Liu ₁ , Kaidian Li ₁ , Wenchao Yang ₁ , Jian Lin ₂ , Ri-Yuan Tang ₁ , Hanhong Xu ₁ , Zhaodong Li _{1,

3}

Affiliation

A novel approach towards the efficient assembly of β-fluoroalkylated arenes is presented here based on Pd/norbornene cooperative catalysis, which features an excellent functional group tolerance, as well as a broad ipso termination scope. The mild reaction conditions enabled the diversity-oriented synthesis (DOS) of the 13 and 14-membered fluorinated macrolactones which is extremely challenging otherwise. This new abstract could be used instead of our old version.

中文翻译：

通过 Pd/降冰片烯协同催化以多样性为导向合成 β-氟烷基化芳烃的模块化方法

本文提出了一种基于 Pd/降冰片烯协同催化的有效组装 β-氟烷基化芳烃的新方法，该方法具有出色的官能团耐受性以及广泛的 ipso 终止范围。温和的反应条件使 13 元和 14 元氟化大环内酯的多样性导向合成 (DOS) 成为可能，否则极具挑战性。这个新的摘要可以用来代替我们的旧版本。

更新日期：2022-09-22

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