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Concentrated Lithium Dodecyl Sulfate Aqueous Electrolytes: Utilizing Self-Assembly and Interfacial Adsorption for Aqueous Li-ion Batteries
ChemElectroChem ( IF 3.5 ) Pub Date : 2022-09-21 , DOI: 10.1002/celc.202200870 Shinji Kondou 1 , Asuka Morinaga 2, 3 , Kei Hashimoto 4 , Yu Katayama 2 , Kaoru Dokko 1, 5 , Masayoshi Watanabe 5 , Kazuhide Ueno 1, 5
ChemElectroChem ( IF 3.5 ) Pub Date : 2022-09-21 , DOI: 10.1002/celc.202200870 Shinji Kondou 1 , Asuka Morinaga 2, 3 , Kei Hashimoto 4 , Yu Katayama 2 , Kaoru Dokko 1, 5 , Masayoshi Watanabe 5 , Kazuhide Ueno 1, 5
Affiliation
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Aqueous Electrolytes for Batteries: The self-assembly of lithium dodecyl sulfate (LiDS) into micelles effectively limited anion diffusion, enabling nearly single Li-ion conduction in the bulk electrolyte. The DS molecules formed a hydrophobic layer at the interface under the electric field, expanding the electrochemical window to 3.0 V. This electrolyte enabled good battery performance of the LiTi2(PO4)3/LiFePO4 full-cell.
中文翻译:
浓缩十二烷基硫酸锂水系电解质:利用自组装和界面吸附制备水系锂离子电池
用于电池的水性电解质:十二烷基硫酸锂 (LiDS) 自组装成胶束有效地限制了阴离子扩散,从而使锂离子在体电解质中几乎单一传导。DS分子在电场作用下在界面处形成疏水层,将电化学窗口扩大到3.0 V。这种电解质使LiTi 2 (PO 4 ) 3 /LiFePO 4全电池具有良好的电池性能。
更新日期:2022-09-21
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
浓缩十二烷基硫酸锂水系电解质:利用自组装和界面吸附制备水系锂离子电池
用于电池的水性电解质:十二烷基硫酸锂 (LiDS) 自组装成胶束有效地限制了阴离子扩散,从而使锂离子在体电解质中几乎单一传导。DS分子在电场作用下在界面处形成疏水层,将电化学窗口扩大到3.0 V。这种电解质使LiTi 2 (PO 4 ) 3 /LiFePO 4全电池具有良好的电池性能。