Decarboxylative Selective Phosphorylation of Aliphatic Acids: A Transition-Metal- and Photocatalyst-Free Avenue to Dialkyl and Trialkyl Phosphine Oxides from White Phosphorus,Angewandte Chemie International Edition

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Decarboxylative Selective Phosphorylation of Aliphatic Acids: A Transition-Metal- and Photocatalyst-Free Avenue to Dialkyl and Trialkyl Phosphine Oxides from White Phosphorus
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-09-16 , DOI: 10.1002/anie.202210334
Fushan Chen ₁ , Mengpei Bai ₁ , Yumeng Zhang ₁ , Weijie Liu ₁ , Xinlei Huangfu ₁ , Yan Liu , Guo Tang ₁ , Yufen Zhao ₁

Affiliation

Functionalization of white phosphorus (P₄) with N-hydroxyphthalimide esters to synthesize dialkylphosphines and trialkylphosphines under transition-metal- and photocatalyst-free conditions is presented. The oxidation products can be isolated in high yield via the air oxidation of alkylated phosphines.

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