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Scalable Electrosynthesis of Formamide through C−N Coupling at the Industrially Relevant Current Density of 120 mA cm−2
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-09-15 , DOI: 10.1002/anie.202213009
Jiang Shao 1 , Nannan Meng 1 , Yuting Wang 1 , Baoshun Zhang 1 , Kaiwen Yang 1 , Cuibo Liu 1 , Yifu Yu 1, 2 , Bin Zhang 1, 2
Affiliation  

Boron-doped diamond catalyst is adopted for electrooxidation synthesis of formamide from methanol and ammonia with high activity and durability. A scale-up 8 L electrolyzer with an external renewable power supply for the production of formamide is designed to enable its scalable production (FE: 33.5 %, output: 36.9 g h−1), which shows the potential for the large-scale electrosynthesis of formamide.

中文翻译:

在工业相关电流密度 120 mA cm-2 下通过 C-N 耦合可扩展的甲酰胺电合成

采用硼掺杂金刚石催化剂由甲醇和氨电氧化合成甲酰胺,具有高活性和耐久性。用于生产甲酰胺的带有外部可再生电源的放大 8 L 电解槽旨在实现其规模化生产(FE:33.5 %,产量:36.9 g h -1),这显示了大规模电合成甲酰胺的潜力甲酰胺。
更新日期:2022-09-15
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