Atomically precise copper nanoclusters as ultrasmall molecular aggregates: Appealing compositions, structures, properties, and applications,Aggregate

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Atomically precise copper nanoclusters as ultrasmall molecular aggregates: Appealing compositions, structures, properties, and applications
Aggregate ( IF 13.9 ) Pub Date : 2022-09-13 , DOI: 10.1002/agt2.266
Leon Li‐Min Zhang _{1,

2} , Wai‐Yeung Wong _{1,

2}

Affiliation

Metal nanoclusters (NCs) are ultrasmall molecular aggregates consisting of dozens to hundreds of metal atoms consolidated by organic ligands, which represent an emerging area of nanoscience. Amide a myriad of metal NCs, copper NCs (CuNCs) comprise a low-cost, high-value subclass that has attracted great attention. The variable copper cores and diversity of protecting ligands have rendered CuNCs interesting molecular aggregates featuring structural and compositional versatility, hence showing distinctive properties and potential applications. In the present review, we have summarized the progress on atomically precise CuNCs that exhibit a range of appealing properties and applications in different fields. This review is expected to provide not only an overview of the current development on atomically precise CuNCs, but also possible directions for the future design of novel CuNCs for fundamental studies and practical applications.

中文翻译：

作为超小分子聚集体的原子精确铜纳米团簇：吸引人的组成、结构、性质和应用

金属纳米团簇（NCs）是由数十至数百个金属原子通过有机配体结合而成的超小分子聚集体，代表了纳米科学的一个新兴领域。在无数的金属 NCs 中，铜 NCs (CuNCs) 包含一个低成本、高价值的子类，引起了极大的关注。可变的铜核和保护配体的多样性使 CuNCs 成为有趣的分子聚集体，具有结构和组成的多样性，因此显示出独特的性质和潜在的应用。在本综述中，我们总结了原子精确 CuNC 的进展，这些 CuNC 在不同领域表现出一系列吸引人的特性和应用。预计这篇综述不仅会概述原子级精确 CuNC 的当前发展，

更新日期：2022-09-13

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