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A Pyridine-Stabilized N-Phosphinoamidinato N-Heterocyclic Carbene-Diboravinyl Cation: Boron Analogue of Vinyl Cation
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2022-09-13 , DOI: 10.1002/anie.202212842
Jun Fan, Pei-Ting Chia, Zheng-Feng Zhang, Ming-Chung Yang, Ming-Der Su, Cheuk-Wai So

A pyridine-stabilized N-phosphinoamidinato N-heterocyclic carbene-diboravinyl cation was obtained through the displacement reaction of the bromide substituent on a diborene derivative using pyridine. This newly formed species was shown to be a boron analogue of the vinyl cation which could be used for the activation of small molecules.

中文翻译:

吡啶稳定的 N-膦基脒基 N-杂环卡宾-二硼乙烯基阳离子:乙烯基阳离子的硼类似物

吡啶稳定的N-膦基脒基N-杂环卡宾-二硼乙烯基阳离子通过溴化物取代基在二硼烯衍生物上的置换反应使用吡啶获得。这种新形成的物质被证明是乙烯基阳离子的硼类似物,可用于活化小分子。
更新日期:2022-09-13
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