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CsB3O4(OH)2: a new deep-ultraviolet birefringent crystal with [B3O4(OH)2] anionic group
Dalton Transactions ( IF 3.5 ) Pub Date : 2022-09-13 , DOI: 10.1039/d2dt02573f
Xinyue Wang 1 , Bingbing Zhang 1 , Daqing Yang 1 , Ying Wang 1
Affiliation  

A new cesium hydroxyborate CsB3O4(OH)2, was designed and synthesized by a hydrothermal method. Remarkably, CsB3O4(OH)2 presents novel [B3O4(OH)2] chains formed by [B3O4(OH)2] fundamental building blocks (FBBs). The report of less common [B3O4(OH)2] FBBs and [B3O4(OH)2] chains in CsB3O4(OH)2 enriches the structural diversity of hydroxyborates. In addition, CsB3O4(OH)2 has a wide transparent window in the DUV spectral range and a large birefringence.

中文翻译:

CsB3O4(OH)2:具有[B3O4(OH)2]阴离子基团的新型深紫外双折射晶体

采用水热法设计合成了一种新型羟基硼酸铯CsB 3 O 4 (OH) 2 。值得注意的是,CsB 3 O 4 (OH) 2呈现出由 [B 3 O 4 (OH) 2 ] 基本构件 (FBB)形成的新型 [B 3 O 4 (OH) 2 ] ∞链。CsB 3 O 4中不太常见的 [B 3 O 4 (OH) 2 ] FBB 和 [B 3 O 4 (OH) 2 ] 链的报告(OH) 2丰富了羟基硼酸盐的结构多样性。此外,CsB 3 O 4 (OH) 2在深紫外光谱范围内具有较宽的透明窗口和较大的双折射。
更新日期:2022-09-16
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