Carbon ( IF 10.5 ) Pub Date : 2022-09-11 , DOI: 10.1016/j.carbon.2022.09.012 Peng Zhang , Liangke Yin , Xiaoyan Yang , Jiaren Wang , Mingming Chi , Jieshan Qiu
Because of abundant oxygen-based groups, natural cotton is adopted as the precursor to in situ fabricate a three-dimensional (3D) Bi2O3-supported carbon fiber aerogel (Bi2O3/CF). The calcination temperature plays an important role in the crystal composition of Bi species and the specific surface area of the aerogel. When the calcination temperature is 800 °C, the Bi2O3/CF product exhibits the highest tetracycline (TC) removal efficiency, including large adsorbability and superior photocatalytic activity. Furthermore, its 3D porous network architecture provides a multidimensional open framework for the free mobility of solution and rapid diffusion of reactants and products. In the flowing system, the 3D Bi2O3/CF aerogel can implement the continuous and stable elimination of pollutants for a long time, and it does not require any separation operation. Consequently, the 3D Bi2O3/CF aerogel is expected as a promising functional material to massively remove organic pollutants from industrial wastewater.
中文翻译:
棉花衍生的 3D 碳纤维气凝胶原位支持 Bi2O3 纳米颗粒作为免分离光催化剂用于抗生素去除
由于含氧基团丰富,采用天然棉作为前驱体原位制备三维(3D)Bi 2 O 3负载碳纤维气凝胶(Bi 2 O 3 /CF)。煅烧温度对Bi物种的晶体组成和气凝胶的比表面积起着重要作用。当煅烧温度为 800 ℃时,Bi 2 O 3/CF 产品表现出最高的四环素 (TC) 去除效率,包括大的吸附性和优异的光催化活性。此外,其 3D 多孔网络架构为溶液的自由流动和反应物和产物的快速扩散提供了多维开放框架。在流动系统中,3D Bi 2 O 3 /CF 气凝胶可以实现长时间连续稳定去除污染物,不需要任何分离操作。因此,3D Bi 2 O 3 /CF 气凝胶有望成为一种很有前途的功能材料,可大量去除工业废水中的有机污染物。